Title : Removal of oxytetracycline antibiotic via photocatalytic process by SnO2/Bi2Sn2O7 nanocatalyst
Abstract:
SnO2/Bi2Sn2O7 heterojunction photocatalyst was fabricated to determine the photocatalytic removal of oxytetracycline antibiotic. Experimental results indicated that the existence of the built-in electric field between SnO2 and Bi2Sn2O7 led to a direct Z-scheme charge transfer. The efficient separation and fast transfer of photogenerated charge carriers contributed to boosting the photocatalytic performance of SnO2/Bi2Sn2O7. The optimal photocatalytic tetracycline degradation efficiency of SnO2/Bi2Sn2O7 was 98 % at a SnO2 to Bi2Sn2O7 ratio of 0.45, at a 1.80 mg/l SnO2/Bi2Sn2O7 concentration at a power of 40 W after 20 min irrdiation. Radical trapping experiments and electron paramagnetic results indicated that the photocatalytic degradation process in SnO2/Bi2Sn2O7 system was modulated by photogenerated electrons, holes and O2− active species. The synthesized composites were characterized by the XRD, TEM, DRS and FTIR spectroscopy. The surface area of C2 composite (42.8 m2 /g) was measure from the nitrogen adsorption/desorption data using Brunauer–Emmett–Teller (BET). The performance enhancement of the photoactivity is because of improved electron-hole separation efciency due to active electron transfer between Bi2Sn2O7 and SnO2 from SnO2/Bi2Sn2O7 composite.
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